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Zogulitsa

Potaziyamu peroxymonosulfate

Kufotokozera Kwachidule:


  • Dzina lazogulitsa:Potaziyamu peroxymonosulfate
  • Mawu ofanana ndi mawu:Potaziyamu peroxymonosulfate,Active Oxygen≥4.5%;Potaziyamu wa hydrogen monopersulfate;Potaziyamu peroxymonosulfate joyce;OXONE, MONOPERSULFATE COMPOUNDOXONE, MONOPERSULFATE COMPOUNDOXONE, MONOPERSULFATE COMPOUNDOXONE, MONOPERSULFATEPossitamosulfatePossiosulfate3Possiosulfate-hydrogen; trioxidan-1-ide;PotassiuM Monopersultate coMpound;Oxone, potaziyamu monopersulfate
  • CAS:70693-62-8
  • MF:Mtengo wa HKO6S
  • MW:168.17
  • EINECS:274-778-7
  • Magulu azinthu:Zachilengedwe
  • Fayilo ya Mol:70693-62-8.mol
  • Tsatanetsatane wa Zamalonda

    Zogulitsa Tags

    adzida1

    Potaziyamu Peroxymonosulfate Chemical Properties

    kachulukidwe 1.15
    kutentha kutentha. Sungani pa <= 20°C.
    kusungunuka 250-300g/l sungunuka
    mawonekedwe cholimba
    mtundu woyera
    Specific Gravity 1.12-1.20
    PH 2-3 (10g/l, H2O, 20℃)
    Kusungunuka kwamadzi Zosungunuka m'madzi (100 mg/ml).
    Zomverera Hygroscopic
    Malire owonetsera ACGIH: TWA 0.1 mg/m3
    Kukhazikika: Wokhazikika.Oxidizer.Zosagwirizana ndi zinthu zoyaka moto, maziko.
    InChIKey HVAHYVDBVDILBL-UHFFFAOYSA-M
    LogP -3.9 pa 25 ℃
    CAS DataBase Reference 70693-62-8(CAS DataBase Reference)
    EPA Substance Registry System Potaziyamu peroxymonosulfate sulphate (K5[HSO3(O2)][SO3(O2)](HSO4)2) (70693-62-8)

    Potaziyamu Peroxymonosulfate Kufotokozera

    Potaziyamu peroxymonosulfate, yemwenso amadziwika kuti potassium monopersulfate kapena potaziyamu peroxodisulfate, ndi amphamvu oxidizing wothandizila ambiri ntchito zosiyanasiyana ntchito.

    Ndi ufa wa crystalline woyera womwe umasungunuka kwambiri m'madzi komanso wosasunthika kutentha.Chimodzi mwazinthu zomwe zimagwiritsidwa ntchito kwambiri ndi potaziyamu persulfate ndi monga oxidizing mu dziwe losambira ndi mankhwala amadzi a spa.Zimathandizira kuchotsa zowononga zachilengedwe, zimapha mabakiteriya, zimachotsa algae ndikuwongolera kumveka bwino kwamadzi.Nthawi zambiri amagulitsidwa pansi pa mayina osiyanasiyana amtundu wa granule kapena piritsi.Potaziyamu peroxymonosulfate imagwiritsidwanso ntchito ngati oxidant ndi mankhwala ophera tizilombo m'njira zosiyanasiyana zamafakitale monga mankhwala amadzi onyansa, zamkati ndi mapepala, komanso kaphatikizidwe ka mankhwala.

    Kuphatikiza apo, imagwiritsidwa ntchito m'malo a labotale kuyeretsa ndi kupha zida ndi malo.Ndikofunika kutenga njira zodzitetezera pogwiritsira ntchito potaziyamu sulfate.Zitha kukwiyitsa maso, khungu ndi kupuma, kotero magalasi, magolovesi ndi mask akulimbikitsidwa.Njira zoyenera zotayiramo ziyeneranso kutsatiridwa pofuna kupewa kuipitsidwa kwa chilengedwe.Ndizofunikira kudziwa kuti potaziyamu peroxymonosulfate sayenera kusokonezedwa ndi potaziyamu sulfate, wothandizila wina wokhala ndi okosijeni yemwe ali ndi katundu wofanana koma kapangidwe kake kosiyana ndi kugwiritsa ntchito.

    Zambiri Zachitetezo

    Zizindikiro Zowopsa O, C
    Ndemanga Zowopsa 8-22-34-42/43-37-35
    Ndemanga za Chitetezo 22-26-36/37/39-45
    RIDADR UN 3260 8/PG 2
    WGK Germany 1
    TSCA Inde
    HS kodi 2833 40 00
    HazardClass 5.1
    PackingGroup III
    Poizoni LD50 pakamwa pa Kalulu: > 2000 mg/kg

    Potaziyamu peroxymonosulfate Kugwiritsa Ntchito Ndi Kaphatikizidwe

    Zochita
    1. Reagent ya catalytic asymmetric Shi epoxidation
    2. Reagent ya kaphatikizidwe ka nitro heteroaromatics m'madzi
    3. Reagent kwa syntheses wa benzoxazoles ndi benzothiazoles ntchito aryl ayodini kudzera CH functionalization ndi CO/S mgwirizano mapangidwe
    4. Reagent yomwe imagwiritsidwa ntchito pa bromolactonization mu asymmetric okwana kaphatikizidwe ka (+)-Dubiusamine C
    5. Reagent ya benzofuran oxidative dearomatization cascade mu kaphatikizidwe kokwanira ka Integrastatin B

    adzi1

    Chemical Properties woyera crystalline ufa
    Ntchito PCB zitsulo pamwamba mankhwala mankhwala ndi madzi mankhwala etc.
    Ntchito Oxone ntchito halogenation wa b-unsaturated carbonyl mankhwala ndi chothandizira m'badwo wa hypervalent ayodini reagents kwa mowa okosijeni.Ndiwogwiritsidwa ntchito mwachangu, komanso kaphatikizidwe kabwino ka oxaziridines.
    Kufotokozera Kwambiri OXONE?, monopersulfate pawiri ndi potaziyamu katatu mchere makamaka ntchito khola, yosavuta kunyamula ndi nontoxic okosijeni.
    Kutentha ndi Kuphulika Zosayaka
    Njira Zoyeretsera Uwu ndi mtundu wokhazikika wa asidi wa Caro ndipo uyenera kukhala ndi> 4.7% ya oxygen yogwira ntchito.Itha kugwiritsidwa ntchito munjira za EtOH/H2O ndi EtOH/AcOH/H2O.Ngati oxygen yogwira ntchito ndiyotsika kwambiri.ndibwino kuti mukonzenso kuchokera ku 1mole ya KHSO5, 0.5mole ya KHSO4 ndi 0.5mole ya K2SO4.[Kennedy & Stock J Org Chem 25 1901 1960, Stephenson US Patent 2,802,722 1957.] Kukonzekera kofulumira kwa asidi wa Caro kumapangidwa ndi kusonkhezera finely powdered potassium persulfate (M 270.3) mu ayezi-wozizira conc H2SO4 ndi ayezi wowonjezera (7mL 7mL) (40-50 g).Imakhala yokhazikika kwa masiku angapo ngati ikuzizira.Khalani kutali ndi zinthu zachilengedwe chifukwa ndi WOTHANDIZA WOTHANDIZA.Kukonzekera mwatsatanetsatane kwa Caro's acid (hypersulfuric acid, H2SO5) mu mawonekedwe a crystalline m ~45o kuchokera ku H2O2 ndi chlorosulfonic acid anafotokozedwa ndi Fehér mu Handbook of Preparative Inorganic Chemistry (Mkonzi. Brauer) Academic Press Vol I p 388 1963.

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